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Lutetium(III) fluoride


Lutetium(III) fluoride


Lutetium(III) fluoride is an inorganic compound with a chemical formula LuF3.

Production

Lutetium(III) fluoride can be produced by reacting lutetium oxide with hydrogen fluoride, or reacting lutetium chloride and hydrofluoric acid:

Lu2O3 + 6 HF → 2 LuF3 + 3 H2O
LuCl3 + 3 HF → LuF3 + 3 HCl

It can also be produced by reacting lutetium sulfide and hydrofluoric acid:

3 Lu
2
S
3
+ 20 HF + (2 + 2x) H
2
O → 2 (H
3
O)Lu
3
F
10
·xH
2
O↓ + 9 H
2
S↑
 (x = 0.9)
(H3O)Lu3F10 → 3 LuF3 + HF↑ + H2O↑

Lutetium oxide and nitrogen trifluoride react at 240 °C to produce LuOF. A second step happens below 460 °C to produce LuF3.

References



Text submitted to CC-BY-SA license. Source: Lutetium(III) fluoride by Wikipedia (Historical)